BINAP 1.1′-Binaphthyl-2.2′-diphemyl phosphine CAS 98327-87-8

Synonyms

BINAP
Binap
(?-Binap
1.1′-Binaphthyl-2.2′-Diphemyl Phosphine
2,2′-BIS(DIPHENYLPHOSPHINO)-1,1′-BINAPHTHYL
(?-2,2-Bis(Diphenylphosphino)-1,1-Binaphthyl
Rac-2,2-Bis(Diphenylphosphino)-1,1-Binaphthyl
2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene
Racemic-2,2′-bis(diphenylphosphino)-1,1′-binaphthy
racemic-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl
S(-)-(1,1′-Binaphthalene-2,2′-Diyl)Bis(Diphenylphosphine)
RACEMIC-2,2”-BIS(DIPHENYLPHOSPHINO)-1,1”-BINAPHTHYL BINAP
2,2′-Bis-(diphenylphosphino)-1,1′-binaphthyl (Racemic BINAP)

CAS

98327-87-8

EINECS

619-338-0

InChIKey

MUALRAIOVNYAIW-UHFFFAOYSA-N

Molarmassa

622.69

Melting Point

283-286°C(lit.)

Boling Point

724.3±55.0 °C(Predicted)

Vattenlöslighet

Soluble in tetrahydrofuran, benzene and dichloromethane. Slightly soluble in ether, methanol and ethanol. Insoluble in water.

Solubility

Chloroform (Slightly, Sonicated), Dichloromethane (Slightly, Heated),

Utseende

White to beige powder

Färg

White to light beige

Merck

14,1223

BRN

5321443

Lagringstillstånd

Keep in dark place,Inert atmosphere,Room temperature

Sensitive

Air Sensitive

MDL

MFCD00010805

Physical and Chemical Properties

Melting point 280-285°C.

Use

Used for asymmetric hydrogenation catalysis, carbonyl reduction, etc. A ligand for the palladium-catalyzed arylamine coupling reaction for the preparation of desmethylthio-colchicine? cicatine. It can be used in combination with Cu(II) to catalyze the addition reaction of arylsulfonamide to produce styrene and olefins. It can also be used for palladium-catalyzed tripyridyl amine reaction.

Risk Codes

36/37/38 – Irritating to eyes, respiratory system and skin.

Safety Description

S22 – Do not breathe dust.
S24/25 – Avoid contact with skin and eyes.
S37/39 – Wear suitable gloves and eye/face protection
S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

WGK Germany

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